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Chapter 15 is devoted to systems of identical particles and the associated quantum statistics. It is shown how the spin (whether integer or half-integer) determines fundamental features of the system’s behavior that cannot be obtained by approximate methods, in particular the exchange effects characteristic of states of two or more identical particles. The spin-symmetry relation is discussed in detail for both the Bose–Einstein and the Fermi–Dirac statistics. Quantum collective phenomena that are a defining feature of condensed matter, including phonons, superconductivity, Bose–Einstein condensates and the quantum Hall effect, are briefly introduced. Since most real quantum systems consist of subsystems in different quantum states that are mixtures of pure states, the chapter includes an introduction to the density matrix, its basic properties and its application to quantum statistics. It concludes with a critical discussion of decoherence and the significance of the collapse of the wave function.
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