Chapter 14 is entirely devoted to the electron spin and an introduction to quantum entanglement. The first part deals with the groundbreaking discovery of spin, its introduction into quantum formalism, and some of its most important effects on atomic spectra, notably the anomalous Zeeman effect. Historically, spin has been considered as an angular momentum that particles can have by the mere fact of their existence, which is called "intrinsic" and does not require any explanation. To address this shortcoming, Section 4 presents a possible explanation for the origin of electron spin as a result of its interaction with the vacuum field. Section 5 introduces the entangled system of two particles with spin, which provides an opportunity to discuss, necessarily schematically, the Schrödinger cat and the Einstein-Podolsky-Rosen thought experiment, as well as the Bell inequalities.

The third chapter examines the capabilities of liquid-state NMR systems for quantum computing. It begins by grounding the reader in the basics of spin dynamics and NMR spectroscopy, followed by a discussion on the encoding of qubits into the spin states of the nucleus of atoms inside molecules. The narrative progresses to describe the implementation of single-qubit gates via external magnetic fields, weaving in key concepts such as the rotating-wave approximation, the Rabi cycle, and pulse shaping. The technique for orchestrating two-qubit gates, leveraging the intrinsic couplings between the spins of nuclei of atoms within a molecule, is subsequently detailed. Additionally, the chapter explains the process of detecting qubits’ states through the collective nuclear magnetization of the NMR sample and outlines the steps for qubit initialization. Attention then shifts to the types of noise that affect NMR quantum computers, shedding light on decoherence and the critical T1 and T2 times. The chapter wraps up by providing a synopsis, evaluating the strengths and weaknesses of liquid-state NMR for quantum applications, and a note on the role of entanglement in quantum computing.

Optical nonlinearity emerges from nonlinear interaction of light with matter. In this chapter, the basic concept and formulation of light‒matter interaction are discussed through a semiclassical approach with the behavior of the optical field classically described by Maxwell’s equations and the state of the material quantum mechanically described by a wave function governed by the Hamiltonian of the material. An optical field interacts with a material through its interaction with the electrons in the material. A Schrödinger electron is nonrelativistic with a nonzero mass, and a Dirac electron is relativistic with a zero mass. The interaction Hamiltonian can be expressed in terms of the vector and scalar potentials by using the Coulomb gauge. It can be expressed in terms of the electric and magnetic fields through multipole expansion as a series of electric and magnetic multipole interactions, with the first term being the electric dipole interaction. The electric polarization of a material induced by an optical field is obtained through density matrix analysis. The optical susceptibility of the material is then obtained from the electric polarization.

Optical nonlinearity manifests nonlinear interaction of an optical field with a material. The origin of optical nonlinearity is the nonlinear response of electrons in a material to an optical field. Macroscopically, the nonlinear optical response of a material is described by an optical polarization that is a nonlinear function of the optical field. This optical polarization is obtained through density matrix analysis by using the interaction Hamiltonian, which can be approximated with electric dipole interaction in most cases. When the interaction Hamiltonian is small compared to the Hamiltonian of the system, it can be treated as a perturbation to the system by expanding the density matrix in a perturbation series and the total optical polarization in terms of a series of polarizations. In most nonlinear optical processes of interest, the perturbation expansion of the polarization is valid and only the three terms of linear, second-order, and third-order polarizations are significant. The perturbation expansion is not valid in the cases of high-order harmonic generation and optical saturation. Then, a full analysis is required.