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Conventionally Heated Microfurnace for the Graphitization of Microgram-Sized Carbon Samples

Published online by Cambridge University Press:  08 November 2016

Bin Yang  and
A M Smith Open the ORCID record for A M Smith [Opens in a new window]
Bin Yang*
Affiliation:
Australian Nuclear Science and Technology Organisation, New Illawarra Road, Lucas Heights, NSW 2234, Australia
A M Smith
Affiliation:
Australian Nuclear Science and Technology Organisation, New Illawarra Road, Lucas Heights, NSW 2234, Australia
*
* Corresponding author. Email: byz@ansto.gov.au.
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Abstract

A new type of miniaturized, externally heated graphitization reaction furnace, the microconventional furnace (MCF), was constructed following our development of the laser heated furnace (LHF). The MCF is comprised of a gas reactor, a cold finger cooling system, and a compact resistive heater, which can raise the temperature of the hot finger to 850°C. The gas reactor is provided with three integrated valves to connect with the hydrogen/vacuum manifold, to isolate the reactor, and to connect with sample vessels. We made two types of MCF: the type 1 furnace (volume of 0.9 mL), with an integral stainless steel cold finger, and the type 2 furnace (volume from 1.3 to 10 mL), with a changeable glass cold finger. The MCF is designed for above atmospheric pressure (up to 2500 mbar) operation to decrease the overall graphitization time and improve the carbon yield. The MCF provides an effective solution for producing graphite from carbon dioxide (CO2) sample gas from 5 to 2000 µg of carbon with only 0.083 μg of 100 pMC extraneous carbon added. Cross-contamination tests show that the MCFs have no memory effect from previous samples.

Keywords

Bosch reactiongraphitizationmicroconventional furnace

Information

Type
Chemical Pretreatment Approaches
Information
Radiocarbon , Volume 59 , Special Issue 3: Proceedings of the 22nd International Radiocarbon Conference (Part 2 of 2) , June 2017 , pp. 859 - 873
Copyright
© 2016 by the Arizona Board of Regents on behalf of the University of Arizona 

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Footnotes

Selected Papers from the 2015 Radiocarbon Conference, Dakar, Senegal, 16–20 November 2015

References

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